Résumé
Barium stars are s-process enriched giants. They owe their chemical peculiarities to a past mass transfer phase. During which they were polluted by their binary companion, which at the time was an AGB star, but is now an extinct white dwarf. Barium stars are thus ideal targets for understanding and constraining the s-process in low and intermediate-mass AGB stars. We derive the abundances of a large number of heavy elements in order to shed light on the conditions of operation of the neutron source responsible for the production of s-elements in the former companions of the barium stars. Adopting a recently used methodology(Neyskens et al. 2015), we analyse a sample of 18 highly enriched barium stars observed with the high-resolution HERMES spectrograph mounted on the MERCATOR telescope (La Palma). We determine the stellar parameters and abundances using MARCS model atmospheres. In particular, we derive the Nb/Zr ratio which was previously shown to be a sensitive thermometer for the s-process nucleosynthesis. Indeed, in barium stars, 93Zr has fully decayed into mono-isotopic 93Nb , so Nb/Zr is a measure of the temperature-sensitive 93Zr/Zr isotopic ratio. HD 28159, previously classified as K5III and initially selected to serve as a reference cool K star for our abundance analysis, turns out to be enriched in s-process elements, and as such is a new barium star. Four stars, characterised by high nitrogen abundances, also tend to have high [Nb/Zr] and [hs/ls] ratios. The derived Zr and Nb abundances provide more accurate constraints on the s-process neutron source, identified to be 13C(alpha,n)16O for barium stars. The comparison with stellar evolution and nucleosynthesis models shows that the investigated barium stars were polluted by a low-mass (2-3 Solar mass) AGB star. HD 100503 is potentially identified as the highest metallicity CEMP-rs star yet discovered