Unraveling the synthesis of homoleptic [Ag(N,N-diaryl-NHC)2]Y (Y = BF4, PF6) complexes by ball-milling

Audrey Beillard; Xavier Bantreil; Thomas-Xavier Métro; Jean Martinez; Frédéric Lamaty

doi:10.1039/C6DT03564G

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Unraveling the synthesis of homoleptic [Ag(N,N-diaryl-NHC)2]Y (Y = BF4, PF6) complexes by ball-milling

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Unraveling the synthesis of homoleptic [Ag(N,N-diaryl-NHC)2]Y (Y = BF4, PF6) complexes by ball-milling

Audrey Beillard, Xavier Bantreil, Thomas-Xavier Métro, Jean Martinez and Frédéric Lamaty

Dalton Transactions, Vol.45(44), pp.17859-17866

2016

DOI: https://doi.org/10.1039/C6DT03564G

Abstract

Silver complexes

homoleptic

ball-mill

mechanochemistry

mechanosynthesis

A user-friendly and general mechanochemical method was developed to access rarely described NHC (N-heterocyclic carbene) silver(I) complexes featuring N,N-diarylimidazol(idin)ene ligands and noncoordinating tetrafluoroborate or hexafluorophosphate counter anions. Comparison with syntheses in solution clearly demonstrated the superiority of the ball-milling conditions.

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Title: Unraveling the synthesis of homoleptic [Ag(N,N-diaryl-NHC)2]Y (Y = BF4, PF6) complexes by ball-milling
Creators - without role: Audrey Beillard - Université de Montpellier, Institut des Biomolécules Max Mousseron - IBMM
Xavier Bantreil - Université de Montpellier, Institut des Biomolécules Max Mousseron - IBMM
Thomas-Xavier Métro - Université de Montpellier, Institut des Biomolécules Max Mousseron - IBMM
Jean Martinez - Université de Montpellier, Institut des Biomolécules Max Mousseron - IBMM
Frédéric Lamaty - Université de Montpellier, Institut des Biomolécules Max Mousseron - IBMM
Publication Details: Dalton Transactions, Vol.45(44), pp.17859-17866
Identifiers: 9938864709311
Academic Unit: Institut des Biomolécules Max Mousseron - IBMM
Language: English
Resource Type: Journal article
Local Fields: hal-02364127