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Unprecedented coupling reaction between two anionic species of a closo -decahydrodecaborate cluster and an Anderson-type polyoxometalate
Journal article   Open access   Peer reviewed

Unprecedented coupling reaction between two anionic species of a closo -decahydrodecaborate cluster and an Anderson-type polyoxometalate

Manal Diab, Ana Mateo, Joumada Al Cheikh, Mohamed Haouas, Alireza Ranjbari, Flavien Bourdreux, Daoud Naoufal, Emmanuel Cadot, Carles Bo and Sébastien Floquet
Dalton Transactions, Vol.49(15), pp.4685-4689
2020
DOI: https://doi.org/10.1039/C9DT04676C

Abstract

Two decahydrodecaborate-functionalized Anderson-Evans polyoxometalates have been synthesized. The compounds have been characterized in solution by ESI-MS, various NMR techniques and electrochemistry, while DFT calculation bring strong support to understand their properties.
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