Tuning the coordination sphere of octahedral Dy( iii ) complexes with silanolate/stannanolate ligands: synthesis, structures and slow relaxation of the magnetization

Jérôme Long; Aleksei Tolpygin; Anton Cherkasov; Yulia Nelyubina; Yannick Guari; Joulia Larionova; Alexander Trifonov

doi:10.1039/D1CE01266E

Back

Journal article

Tuning the coordination sphere of octahedral Dy( iii ) complexes with silanolate/stannanolate ligands: synthesis, structures and slow relaxation of the magnetization

Jérôme Long, Aleksei Tolpygin, Anton Cherkasov, Yulia Nelyubina, Yannick Guari, Joulia Larionova and Alexander Trifonov

CrystEngComm, Vol.23(47), pp.8351-8359

06/12/2021

DOI: https://doi.org/10.1039/D1CE01266E

Abstract

This study reports four SMMs based on silanolate or stannanolate ligands cis -[Dy(OSiPh 3 ) 2 (THF) 4 ][BPh 4 ]·THF·C 6 H 6 (1), cis -[Dy(OSnPh 3 ) 2 (THF) 4 ][BPh 4 ]·THF·C 6 H 6· C 6 H 14 (2), fac -[Dy(OSiPh 3 ) 3 (THF) 3 ]·THF (3) and fac -[Dy(OSiPh 3 ) 3 (bipy)(THF)]·THF (4).

Files and links (1)

url

Find in HALView

Metrics

1 Record Views

Details

Title: Tuning the coordination sphere of octahedral Dy( iii ) complexes with silanolate/stannanolate ligands: synthesis, structures and slow relaxation of the magnetization
Creators - without role: Jérôme Long - Université de Montpellier, Institut Charles Gerhardt Montpellier - ICGM
Aleksei Tolpygin - G.A. Razuvaev Institute of Organometallic Chemistry
Anton Cherkasov - G.A. Razuvaev Institute of Organometallic Chemistry
Yulia Nelyubina - A. N. Nesmeyanov Institute of Organoelement Compounds
Yannick Guari - Université de Montpellier, Institut Charles Gerhardt Montpellier - ICGM
Joulia Larionova - Université de Montpellier, Institut Charles Gerhardt Montpellier - ICGM
Alexander Trifonov - G.A. Razuvaev Institute of Organometallic Chemistry
Publication Details: CrystEngComm, Vol.23(47), pp.8351-8359
Identifiers: 9943983509311
Academic Unit: Institut Charles Gerhardt Montpellier - ICGM
Language: English
Resource Type: Journal article
Local Fields: hal-03472534