Abstract
We describe herein the unprecedented reactivity of N-carboxy derivatives of 2,5-diketopiperazines (DKPs). The reaction of these derivatives under basic conditions led to novel substituted pyrrolidine-2,4-diones (1).
- Title
- Transannular Rearrangement of Activated Lactams: Stereoselective Synthesis of Substituted Pyrrolidine-2,4-diones from Diketopiperazines
- Creators - without role
- Daniel Farran - Université de Montpellier, Institut des Biomolécules Max Mousseron - IBMMIsabelle Parrot - Université de Montpellier, Institut des Biomolécules Max Mousseron - IBMMJean Martinez - Université de Montpellier, Institut des Biomolécules Max Mousseron - IBMMGeorges Dewynter - Université de Montpellier, Institut des Biomolécules Max Mousseron - IBMM
- Publication Details
- Angewandte Chemie International Edition, Vol.46, pp.7488-7490
- Identifiers
- 9938584809311
- Academic Unit
- Institut des Biomolécules Max Mousseron - IBMM
- Language
- English
- Resource Type
- Journal article
- Local Fields
- hal-00359100