Titanium alkoxyimido (Ti=N-OR) complexes: reductive N-O bond cleavage at the boundary between hydrazide and peroxide ligands

Andrew D. Schwarz; Ainara Nova-Flores; Eric Clot; Philip Mountford

doi:10.1039/c1cc10862j

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Titanium alkoxyimido (Ti=N-OR) complexes: reductive N-O bond cleavage at the boundary between hydrazide and peroxide ligands

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Titanium alkoxyimido (Ti=N-OR) complexes: reductive N-O bond cleavage at the boundary between hydrazide and peroxide ligands

Andrew D. Schwarz, Ainara Nova-Flores, Eric Clot and Philip Mountford

Chemical Communications, Vol.47, pp.4926-4928

14/04/2011

DOI: https://doi.org/10.1039/c1cc10862j

Abstract

The first Group 4 alkoxyimido compounds are reported. The Ti=N-OtBu group in Ti(N2NMe)(NOtBu)(py) undergoes facile 2-electron N-O bond cleavage with PhCCMe as the reductant to form a 1,2-diamidoalkene group via two highly selective N-C bond forming events.

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Title: Titanium alkoxyimido (Ti=N-OR) complexes: reductive N-O bond cleavage at the boundary between hydrazide and peroxide ligands
Creators - without role: Andrew D. Schwarz - University of Oxford
Ainara Nova-Flores - Université de Montpellier, Institut Charles Gerhardt Montpellier - ICGM
Eric Clot - Université de Montpellier, Institut Charles Gerhardt Montpellier - ICGM
Philip Mountford - University of Oxford
Publication Details: Chemical Communications, Vol.47, pp.4926-4928
Identifiers: 9943288009311
Academic Unit: Institut Charles Gerhardt Montpellier - ICGM
Language: English
Resource Type: Journal article
Local Fields: hal-00586606