The relationship between the conformational degree of freedom of template-containing threads and slippage in the formation of [2]rotaxane building blocks

B. Riss-Yaw; C. Clavel; Ph. Laurent; F. Coutrot

doi:10.1039/c7cc06598a

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The relationship between the conformational degree of freedom of template-containing threads and slippage in the formation of [2]rotaxane building blocks

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The relationship between the conformational degree of freedom of template-containing threads and slippage in the formation of [2]rotaxane building blocks

B. Riss-Yaw, C. Clavel, Ph. Laurent and F. Coutrot

Chemical Communications, Vol.53(79), pp.10874 - 10877

2017

DOI: https://doi.org/10.1039/c7cc06598a

PMID: 28926040

Abstract

rotaxane

slippage

N-hydroxysuccinimide

DB24C8

A straightforward slippage strategy has been used for the synthesis of three [2]rotaxane building blocks that all contain anammonium template for the dibenzo-24-crown-8 macrocycle and an N-hydroxysuccinimide end. The kinetic rate of the slipping-on process proved to be highly dependent on both the length and flexibility of the thread.

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Title: The relationship between the conformational degree of freedom of template-containing threads and slippage in the formation of [2]rotaxane building blocks
Creators - without role: B. Riss-Yaw - Université de Montpellier, Institut des Biomolécules Max Mousseron - IBMM
C. Clavel - Université de Montpellier, Institut des Biomolécules Max Mousseron - IBMM
Ph. Laurent - Université de Montpellier, Institut des Biomolécules Max Mousseron - IBMM
F. Coutrot - Université de Montpellier, Institut des Biomolécules Max Mousseron - IBMM
Publication Details: Chemical Communications, Vol.53(79), pp.10874 - 10877
Identifiers: 9942233109311
Academic Unit: Institut des Biomolécules Max Mousseron - IBMM
Language: English
Resource Type: Journal article
Local Fields: hal-01616749