The organocatalytic ring-opening polymerization of N-tosyl aziridines by an N-heterocyclic carbene

Camille Bakkali-Hassani; Elisabeth Rieger; Joan Vignolle; Frederik R. Wurm; Stéphane Carlotti; Daniel Taton

doi:10.1039/c6cc04323b

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The organocatalytic ring-opening polymerization of N-tosyl aziridines by an N-heterocyclic carbene

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The organocatalytic ring-opening polymerization of N-tosyl aziridines by an N-heterocyclic carbene

Camille Bakkali-Hassani, Elisabeth Rieger, Joan Vignolle, Frederik R. Wurm, Stéphane Carlotti et Daniel Taton

Chemical communications (Cambridge, England), Vol.52(62), pp.9719-9722

11/08/2016

DOI: https://doi.org/10.1039/c6cc04323b

PMID: 27411406

Résumé

Chemical Sciences

Polymers

The ring-opening polymerization of N-tosyl aziridines, in the presence of 1,3-bis(isopropyl)-4,5(dimethyflimidazol-2-ylidene as an organocatalyst and an N-tosyl secondary amine as initiator mimicking the growing chain, provides the first metal-free route to well defined poly(aziridine)s (PAz) and related PAz-based block copolymers.

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Titre: The organocatalytic ring-opening polymerization of N-tosyl aziridines by an N-heterocyclic carbene
Créateurs - sans rôle: Camille Bakkali-Hassani - Laboratoire de Chimie des Polymères Organiques
Elisabeth Rieger - Max-Planck-Institut für Polymerforschung / Max Planck Institute for Polymer Research
Joan Vignolle - Laboratoire de Chimie des Polymères Organiques
Frederik R. Wurm - Max Planck Institute for Polymer Research
Stéphane Carlotti - Laboratoire de Chimie des Polymères Organiques
Daniel Taton - Laboratoire de Chimie des Polymères Organiques
Détails de publication: Chemical communications (Cambridge, England), Vol.52(62), pp.9719-9722
Éditeur: Royal Society of Chemistry
Nombre de pages: 4
Identifiants: 99138921309311
Unité académique: Institut Charles Gerhardt Montpellier - ICGM
Langue: English
Type de ressource: Journal article