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Synthesis, structure, magnetic and luminescence properties of two dysprosium single-molecule magnets based on phenoxide dye ligands
Article de revue   Open Access

Synthesis, structure, magnetic and luminescence properties of two dysprosium single-molecule magnets based on phenoxide dye ligands

Jérome Long, Alexander Selikhov, Ekaterina Mamontova, Konstantin A. Lyssenko, Yannick Guari, Joulia Larionova et Alexander A. Trifonov
CrystEngComm, Vol.22(11), pp.1909-1913
2020

Résumé

We report here two dysprosium complexes based on phenoxidebased emissive ligands 1-(2,4-dimetylphenylazo)-2-naphtholate (L1) and anthracenolate (L2). While 1 is a dinuclear homoleptic complex [Dy 2 (L1) 6 ]•2C 7 H 8 exhibiting a zero-field slow relaxation of the magnetization, 2 is a mononuclear complex [Dy(L2) 3 (py) 3 ] (py = pyridine) showing a field-induced relaxation.

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