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Synthesis, resolution, and determination of absolute configuration of protected α-ethynylphenylalanine enantiomers
Journal article   Open access   Peer reviewed

Synthesis, resolution, and determination of absolute configuration of protected α-ethynylphenylalanine enantiomers

Z Benfodda, David Bénimèlis, Marion Jean, Jean-Valère Naubron, Valerie Rolland and Patrick Meffre
Amino Acids, Vol.47(5), pp.899-907
05/2015

Abstract

α -Ethynylphenylalanine Chiral HPLC resolution Absolute configuration Unsaturated amino acid Quaternary amino acids
Racemic-protected α-ethynylphenylalanine was synthesized from dl-2-benzylserine using α-benzylserinal as key intermediate and was uccessfully resolved by HPLC on a chiral stationary phase at a semipreparative scale. The absolute configuration of both enantiomers was determined by vibrational circular dichroism.
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