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Synthesis of a Linear Assembly Consisting of a Central Ru(Phen)32+ Derivative and Two Peripheral Porphyrins
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Synthesis of a Linear Assembly Consisting of a Central Ru(Phen)32+ Derivative and Two Peripheral Porphyrins

Xavier J Salom-Roig, Jean-Claude Chambron, Christine Goze, Valérie Heitz, Jean-Pierre Sauvage, Gilles Hanquet, Sonia Lemeitour et Guy Solladié
European Journal of Organic Chemistry, Vol.2002(19), pp.3276-3280
21/01/2002

Résumé

Isomerisation Lewis acids Oxygen heterocycles
2-(2-Tetrahydrofurylidene)propionates, usually obtained only in the more stable (E) configuration 1, were efficiently isomerised into their (Z) isomers 2 by use of Lewis acids or metallated bases. The (E)/(Z) isomerisation was governed by different factors (type of chelating agent, nature and steric demand of the α,β-unsaturated group). We demonstrated that judicious selection of the α,β-unsaturated group, in combina

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