Synthesis of All Carbon Linked Glycoside Clusters Round Benzene Scaffold via Sonogashira-Heck-Cassar Cross-Coupling of Iodobenzenes with Ethynyl C-Glycosides

Alessandro Dondoni; Alberto Marra; Maria Grazia Zampolli

doi:10.1055/s-2002-34885

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Synthesis of All Carbon Linked Glycoside Clusters Round Benzene Scaffold via Sonogashira-Heck-Cassar Cross-Coupling of Iodobenzenes with Ethynyl C-Glycosides

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Synthesis of All Carbon Linked Glycoside Clusters Round Benzene Scaffold via Sonogashira-Heck-Cassar Cross-Coupling of Iodobenzenes with Ethynyl C-Glycosides

Alessandro Dondoni, Alberto Marra et Maria Grazia Zampolli

Synlett, Vol.2002(11), pp.1850-1854

2002

DOI: https://doi.org/10.1055/s-2002-34885

Résumé

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Abstract The Pd-catalyzed carbon-carbon bond forming reaction between ethynyl C-glycosides and polyiodinated benzenes (Sonogashira-Heck-Cassar coupling) allows the introduction of various ethynylene glycoside chains on the phenyl ring thus creating glycoside clusters wherein the sugar moieties are linked to the benzene ring by an all carbon tether.

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Titre: Synthesis of All Carbon Linked Glycoside Clusters Round Benzene Scaffold via Sonogashira-Heck-Cassar Cross-Coupling of Iodobenzenes with Ethynyl C-Glycosides
Créateurs - sans rôle: Alessandro Dondoni
Alberto Marra
Maria Grazia Zampolli
Détails de publication: Synlett, Vol.2002(11), pp.1850-1854
Identifiants: 99163234509311
Unité académique: Institut des Biomolécules Max Mousseron - IBMM
Langue: English
Type de ressource: Journal article