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Synthesis of 3,6-Divinyl-1,2,4,5-Tetrazine, the First Member of the Elusive Vinyltetrazine Family
Journal article   Open access   Peer reviewed

Synthesis of 3,6-Divinyl-1,2,4,5-Tetrazine, the First Member of the Elusive Vinyltetrazine Family

Stéphanie Pican, Vincent Lapinte, Jean-François Pilard, Eric Pasquinet, Lionel Beller, Laurent Fontaine and Didier Poullain
SYNLETT, (5), pp.731-734
17/02/2009
DOI: https://doi.org/10.1055/s-0028-1087818

Abstract

azo compounds condensation cyclizations fused ring systems heterocycles
The synthesis of the first vinyltetrazine derivative is ­described. 3,6-Divinyl-1,2,4,5-tetrazine was obtained following a methodology involving cyclization from an imidate and use of 2-phenylsulfonylethyl groups as masked vinyl entities. The first properties of this unique compound are reported.
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