Abstract
New phosphonated cross-linked polymers were synthesized from telomers obtained by reaction between 10-undecenol and dialkyl hydrogenphosphonates. Telomers were studied using MALDI-TOF MS. It was proven that side products were produced, corresponding to cross-esterification reactions of dialkyl hydrogenphosphonate on telomers and to radical additions of telomer on 10-undecenol. The same behavior was also observed with allyl alcohol. Telomers were then converted to resins by methacrylation reactions. Finally, photopolymerization of the different resins synthesized was achieved and influence of the nature of the phosphonate group (diester, monoacid and diacid) was also evaluated.