Synthesis and complexation of heptafluoroisopropyldiphenylphosphine

Lesley C. Lewis-Alleyne; Makeba B. Murphy-Jolly; Xavier F. Le Goff; Andrew J. M. Caffyn

doi:10.1039/b918348e

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Synthesis and complexation of heptafluoroisopropyldiphenylphosphine

Article de revue scientifique

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Synthesis and complexation of heptafluoroisopropyldiphenylphosphine

Lesley C. Lewis-Alleyne, Makeba B. Murphy-Jolly, Xavier F. Le Goff et Andrew J. M. Caffyn

Dalton transactions : an international journal of inorganic chemistry, Vol.39(5), p.1198-1200

01/01/2010

DOI: https://doi.org/10.1039/b918348e

PMID: 20104344

Résumé

Chemistry

Chemistry, Inorganic & Nuclear

Physical Sciences

Science & Technology

We report a one-step synthesis of the phosphine, (PPh2C3F7)-C-i from commercially available precursors. The stereoelectronic properties of the phosphine were probed by coordination to transition metals. Mo(CO)(5)(PPh2C3F7)-C-i was synthesised and the synthesis and structure of trans-PtCl2((PPh2C3F7)-C-i)(2) are described. (PPh2C3F7)-C-i was found to be a bulky electron-withdrawing ligand.

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Détails

Titre: Synthesis and complexation of heptafluoroisopropyldiphenylphosphine
Créateurs - sans rôle: Lesley C. Lewis-Alleyne - Univ W Indies, Dept Chem, St Augustine, Trinidad Tobago
Makeba B. Murphy-Jolly - Univ W Indies, Dept Chem, St Augustine, Trinidad Tobago
Xavier F. Le Goff - Ecole Polytech, CNRS, UMR 7653, Lab Heteroelements & Coordinat, F-91128 Palaiseau, France
Andrew J. M. Caffyn - Univ W Indies, Dept Chem, St Augustine, Trinidad Tobago
Détails de publication: Dalton transactions : an international journal of inorganic chemistry, Vol.39(5), p.1198-1200
Éditeur: Royal Soc Chemistry
Nombre de pages: 3
Identifiants: 99233866409311
Unité académique: ICSM - Institut de Chimie Séparative de Marcoule
Langue: Anglais
Type de ressource: Article de revue scientifique