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Synthesis and characterization of Aza222-based polymers for the removal of mercury from aqueous solutions
Article de revue   Avec comité de lecture

Synthesis and characterization of Aza222-based polymers for the removal of mercury from aqueous solutions

Mikhail Y. Redko, Karrie M. Manes, Julian S. Taurozzi, James E. Jackson et Volodymyr V. Tarabara
Reactive & functional polymers, Vol.74(1), pp.90-100
01/2014

Résumé

Cryptand-metal binding Mercury adsorption Mercury–polyamine stability constant Peraza[2.2.2]cryptand Polyamine
Polymeric materials for mercury complexation have been prepared by cross-linking 1,4,7,10,13,16,21,24-octaazabicyclo[8.8.8]hexacosane (H6Aza222) with α,α′-dichloro-p-xylene and other multidentate electrophiles. Bulk and microporous p-xylylene-Aza222 were shown to be effective at binding divalent mercury cations from aqueous solutions of HgCl2 or Na2HgI4. The complexants were regenerable using solutions of HCl or Na2S.

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