Structure and ion conducting properties of mixed-alkali Na3– xLi xInCl6 solid electrolytes

Dat Le Thanh; Long Hoang Bao Nguyen; Emmanuelle Suard; Romain Berthelot

doi:10.1039/D5DT00817D

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Structure and ion conducting properties of mixed-alkali Na<sub>3– x</sub>Li<sub> x</sub>InCl<sub>6</sub> solid electrolytes

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Structure and ion conducting properties of mixed-alkali Na_{3– x}Li_xInCl₆ solid electrolytes

Dat Le Thanh, Long Hoang Bao Nguyen, Emmanuelle Suard and Romain Berthelot

Dalton Transactions, Vol.54(21), pp.8405-8409

2025

DOI: https://doi.org/10.1039/D5DT00817D

Abstract

Ball-milled and annealed Na_{3– x}Li_xInCl₆ samples exhibit a solubility limit at x = 0.6 and a monoclinic-to-trigonal phase transition. Neutron diffraction and impedance spectroscopy suggest a connected Li$^+$ network with enhanced ionic conductivity.

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Title: Structure and ion conducting properties of mixed-alkali Na_{3– x}Li_xInCl₆ solid electrolytes
Creators - without role: Dat Le Thanh - Université de Montpellier, Institut Charles Gerhardt Montpellier - ICGM
Long Hoang Bao Nguyen - École Nationale Supérieure de Chimie de Montpellier
Emmanuelle Suard - Institut Laue-Langevin
Romain Berthelot - Université de Montpellier, Institut Charles Gerhardt Montpellier - ICGM
Publication Details: Dalton Transactions, Vol.54(21), pp.8405-8409
Identifiers: 9934189309311
Academic Unit: Institut Charles Gerhardt Montpellier - ICGM
Language: English
Resource Type: Journal article
Local Fields: hal-05086692