Single-molecule magnet behaviour in a Dy( iii ) pentagonal bipyramidal complex with a quasi-linear Cl–Dy–Cl sequence

Jérôme Long; Alexander Selikhov; Ekaterina Mamontova; Konstantin A. Lyssenko; Yannick Guari; Joulia Larionova; Alexander A. Trifonov

doi:10.1039/C8DT04098B

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Single-molecule magnet behaviour in a Dy( iii ) pentagonal bipyramidal complex with a quasi-linear Cl–Dy–Cl sequence

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Single-molecule magnet behaviour in a Dy( iii ) pentagonal bipyramidal complex with a quasi-linear Cl–Dy–Cl sequence

Jérôme Long, Alexander Selikhov, Ekaterina Mamontova, Konstantin A. Lyssenko, Yannick Guari, Joulia Larionova and Alexander A. Trifonov

Dalton Transactions, Vol.48(1), pp.35-39

01/2019

DOI: https://doi.org/10.1039/C8DT04098B

Abstract

We report the synthesis and magnetic investigation of a dysprosium pentagonal bipyramidal complex [Dy(THF)5Cl2][BPh4] (1) exhibiting a linear Cl–Dy–Cl sequence suitable for providing a coordination environment allowing a zero-field slow relaxation of the magnetization. Besides, the complex also shows dual luminescence originating from [BPh4]− and Dy3+.

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Title: Single-molecule magnet behaviour in a Dy( iii ) pentagonal bipyramidal complex with a quasi-linear Cl–Dy–Cl sequence
Creators - without role: Jérôme Long - Université de Montpellier, Institut Charles Gerhardt Montpellier - ICGM
Alexander Selikhov - G.A. Razuvaev Institute of Organometallic Chemistry
Ekaterina Mamontova - Université de Montpellier, Institut Charles Gerhardt Montpellier - ICGM
Konstantin A. Lyssenko - A. N. Nesmeyanov Institute of Organoelement Compounds
Yannick Guari - Université de Montpellier, Institut Charles Gerhardt Montpellier - ICGM
Joulia Larionova - Université de Montpellier, Institut Charles Gerhardt Montpellier - ICGM
Alexander A. Trifonov - G.A. Razuvaev Institute of Organometallic Chemistry
Publication Details: Dalton Transactions, Vol.48(1), pp.35-39
Identifiers: 9946960409311
Academic Unit: Institut Charles Gerhardt Montpellier - ICGM
Language: English
Resource Type: Journal article
Local Fields: hal-01960079