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Selective one-pot synthesis of symmetrical and unsymmetrical di- and triarylamines with a ligandless copper catalytic system
Journal article   Peer reviewed

Selective one-pot synthesis of symmetrical and unsymmetrical di- and triarylamines with a ligandless copper catalytic system

Anis Tlili, Florian Monnier and Marc Taillefer
Chemical Communications, Vol.48, pp.6408-6410
28/05/2012

Abstract

amination selective diarylamines triarylamines copper homogeneous catalysis
The one-pot synthesis of various symmetrical or unsymmetrical di- or triarylamines using aryl iodides or bromides and LiNH2 as ammonia source is reported. This highly selective method is based, for the first time, on a cheap copper-catalyzed system, which does not require the presence of any additional ligand.
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