Selective carbon-phosphorus bond cleavage: expanding the toolbox for accessing bulky divalent lanthanoid sandwich complexes

Angus C G Shephard; Daisy P Daniels; Glen B Deacon; Zhifang Guo; Florian Jaroschik; Peter C Junk

doi:10.1039/d2cc00698g

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Selective carbon-phosphorus bond cleavage: expanding the toolbox for accessing bulky divalent lanthanoid sandwich complexes

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Selective carbon-phosphorus bond cleavage: expanding the toolbox for accessing bulky divalent lanthanoid sandwich complexes

Angus C G Shephard, Daisy P Daniels, Glen B Deacon, Zhifang Guo, Florian Jaroschik et Peter C Junk

Chemical communications (Cambridge, England), Vol.58(27), pp.4344-4347

31/03/2022

DOI: https://doi.org/10.1039/d2cc00698g

PMID: 35293913

Résumé

The synthesis of two new tetra- and penta-phenycyclopentadienyldiphenylphosphine pro-ligands which readily undergo selective C-P bond cleavage has allowed for the facile synthesis of bulky divalent octa- and deca-phenylmetallocenes of europium, ytterbium and samarium.

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Titre: Selective carbon-phosphorus bond cleavage: expanding the toolbox for accessing bulky divalent lanthanoid sandwich complexes
Créateurs - sans rôle: Angus C G Shephard - College of Science & Engineering, James Cook University, Townsville, QLD, 4811, Australia. peter.junk@jcu.edu.au
Daisy P Daniels - Monash University
Glen B Deacon - School of Chemistry, Monash University, Clayton, VIC, 3800, Australia
Zhifang Guo - James Cook University
Florian Jaroschik - ICGM, Univ Montpellier, CNRS, ENSCM, Montpellier, France
Peter C Junk - College of Science & Engineering, James Cook University, Townsville, QLD, 4811, Australia. peter.junk@jcu.edu.au
Détails de publication: Chemical communications (Cambridge, England), Vol.58(27), pp.4344-4347
Identifiants: 99158346209311
Unité académique: Institut Charles Gerhardt Montpellier - ICGM
Langue: English
Type de ressource: Journal article