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Selective Reduction of Amino Allenephosphonates: Preparation of α-Amino Vinylphosphonates
Article de revue   Avec comité de lecture

Selective Reduction of Amino Allenephosphonates: Preparation of α-Amino Vinylphosphonates

Pauline Adler, Filipe Gomes, Antoine Fadel et Nicolas Rabasso
European journal of organic chemistry, Vol.2013(33), pp.7546-7555
11/2013
DOI: https://doi.org/10.1002/ejoc.201300904

Résumé

Chemistry Chemistry, Organic Physical Sciences Science & Technology
-Amino vinylphosphonates were prepared by chemo- and stereoselective reduction of -amino allenephosphonates. Our results showed that the substituents on the allene, phosphonate, and nitrogen moieties affected the stereoselectivity of the reduction. Z--Amino vinylphosphonates were prepared with good selectivities up to > 95:5.

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