Logo image
Sign in
Regioselective ester cleavage during the preparation of bisphosphonate methacrylate monomers
Journal article   Open access   Peer reviewed

Regioselective ester cleavage during the preparation of bisphosphonate methacrylate monomers

Kamel Chougrani, Gilles Niel, Bernard Boutevin and Ghislain David
Beilstein Journal of Organic Chemistry, Vol.7, pp.364-368
03/2011

Abstract

New functional monomers bearing a methacrylate, a bisphosphonate function and, for most, an internal carboxylate group, were prepared for incorporation into copolymers with adhesive or anticorrosive properties. Methanolysis of some trimethylsilyl bisphosphonate esters not only deprotects the desired bisphosphonate function but also regioselectively cleaves the alkyl ester function without affecting the methacrylate ester.
url
Find in HALView
url
https://doi.org/10.3762/bjoc.7.46View
Published (Version of record) Open

Metrics

1 Record Views

Details

Logo image