Regio- and stereospecificity in radical cascade cyclizations of TMS-alcyne containing allyl bromomethyldimethylsilyl ethers

Florence Bedos-Belval; Claude Chavis; Alain Fruchier; Jean-Louis Montero; Marc A. Lucas

doi:10.1016/S0040-4039(98)01107-1

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Regio- and stereospecificity in radical cascade cyclizations of TMS-alcyne containing allyl bromomethyldimethylsilyl ethers

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Regio- and stereospecificity in radical cascade cyclizations of TMS-alcyne containing allyl bromomethyldimethylsilyl ethers

Florence Bedos-Belval, Claude Chavis, Alain Fruchier, Jean-Louis Montero and Marc A. Lucas

Tetrahedron Letters, Vol.39(30), pp.5367-5368

07/1998

DOI: https://doi.org/10.1016/S0040-4039(98)01107-1

Abstract

TMS-alcyne

Allyl bromomethyldimethylsilyl ethers

Tandem radical cyclization of (E) and (Z) TMS-homopropargyl allyl bromomethyl-dimethylsilyl ethers is reported to provide an all-cis substituted vinylcyclopentanol 5. Regio- and stereospecificity are discussed.

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Title: Regio- and stereospecificity in radical cascade cyclizations of TMS-alcyne containing allyl bromomethyldimethylsilyl ethers
Creators - without role: Florence Bedos-Belval - Université de Montpellier
Claude Chavis - Université de Montpellier
Alain Fruchier - École Nationale Supérieure de Chimie de Montpellier
Jean-Louis Montero - Laboratoire de Chimie
Marc A. Lucas - Université de Montpellier
Publication Details: Tetrahedron Letters, Vol.39(30), pp.5367-5368
Identifiers: 9942707509311
Academic Unit: Université de Montpellier
Language: English
Resource Type: Journal article
Local Fields: hal-02444163