Abstract
Burning a water-in-oil emulsion enables reduction in solid and gaseous pollutants in comparison with neat oil. In the emulsion, Heavy Fuel-Oil and water lie in distinct phases, having a high difference in boiling point (up to 200 K). In an emulsion droplet injected and subsequently heated inside a flame, the internal water droplets are enclosed inside the emulsion and do not systematically vaporise at boiling point. They are known to reach a metastable state, breaking up at a temperature below the spinodal limit of water. From this moment, the surrounding Fuel-Oil is fragmented into numerous faster and smaller droplets by the suddenly expanding steam. This physical phenomenon is called ''micro-explosion''. This work demonstrates a numerical modelisation Of unsteady heat and mass transfer at the surface and inside of the emulsion droplet, and provides a prediction of its micro-explosion delay, using homogeneous nucleation hypothesis. This assumption of homogeneous nucleation for internal water droplets matches the use of a ''drop tower'' experimental facility. Finally, comparisons between predicted ranges for micro-explosion delays and experimental delays from literature are discussed, along with combustion parameters (ambient temperature, relative velocity) and combustible emulsion parameters. As a result, the experimental and numerical micro-explosion delays decrease with liquid or ambient temperature and relative velocity, and increase with water content and radius of emulsion droplet. Their low average deviation reveals the accuracy of the assumption of homogeneous nucleation in the considered situations. (C) 2008 Elsevier Masson SAS. All rights reserved.