Résumé
The use of a photo-electrochemical cell (PEC) to produce hydrogen from wastewater is a promising innovation. In this context, this study investigates the impact of a pollutant on the photo-electrochemical properties of sol-gel synthesized TiO 2 and TiO 2 -Co 3 O 4 thin films for hydrogen production in a polluted electrolyte. Combining the photocatalytic properties of TiO 2 with the electronic properties of Co 3 O 4 offers an effective solution for achieving effective photoelectrochemical properties in polluted environments. Nevertheless, despite the lowest photocatalytic activity, the hybrid thin film TiO 2 -Co 3 O 4 with the highest Ti/Co ratio (1:0.5) shows the most promising performance with simultaneous 11.4 µmol.cm -2 .h -1 H 2 production and 12% acid orange 7 degradation after 3 h irradiation under xenon light without the use of any sacrificial agent. This indicates that the electronic conductivity provided by the presence of Co 3 O 4 is a critical property for achieving optimal performance in PEC coupling for hydrogen production and wastewater treatment.
Sol-gel synthesis, TiO 2 (-Co 3 O 4 ) thin films, Water splitting, Photo-electrochemical cell, Wastewater treatment, Hydrogen production