One-pot multifunctional polyesters by continuous flow organocatalysed ring-opening polymerisation for targeted and tunable materials design

Camille Bakkali-Hassani; Jordan P. Hooker; Pieter-Jan Voorter; Maarten Rubens; Neil R. Cameron; Tanja Junkers

doi:10.1039/D2PY00088A

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One-pot multifunctional polyesters by continuous flow organocatalysed ring-opening polymerisation for targeted and tunable materials design

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One-pot multifunctional polyesters by continuous flow organocatalysed ring-opening polymerisation for targeted and tunable materials design

Camille Bakkali-Hassani, Jordan P. Hooker, Pieter-Jan Voorter, Maarten Rubens, Neil R. Cameron et Tanja Junkers

Polymer chemistry, Vol.13(10), pp.1387-1393

08/03/2022

DOI: https://doi.org/10.1039/D2PY00088A

Résumé

Targeted and tunable access to biodegradable polymers will be vital for their continued adoption and use in modern materials applications. Herein we report a platform for the synthesis of well-defined, curable biodegradable polymer precursors, prepared in a controlled manner via continuous flow ring-opening polymerisation/post-modification reactions of ε-caprolactone and l -lactide. Polymer architectures are characterised by 1 H NMR spectroscopy, ESI mass spectrometry, and size exclusion chromatography, and their potential application in materials synthesis is subsequently highlighted by employing them as precursors to prepare networks and polymerised high internal phase emulsions (polyHIPEs) via an emulsion templating strategy using photo-initiated thiol–ene click reaction.

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Titre: One-pot multifunctional polyesters by continuous flow organocatalysed ring-opening polymerisation for targeted and tunable materials design
Créateurs - sans rôle: Camille Bakkali-Hassani - Polymer Reaction Design Group, School of Chemistry, Monash University, 19 Rainforest Walk, Clayton, VIC 3800, Australia, Department of Materials Science and Engineering, Monash University, Clayton, VIC 3800, Australia
Jordan P. Hooker - Polymer Reaction Design Group, School of Chemistry, Monash University, 19 Rainforest Walk, Clayton, VIC 3800, Australia, Department of Materials Science and Engineering, Monash University, Clayton, VIC 3800, Australia
Pieter-Jan Voorter - Polymer Reaction Design Group, School of Chemistry, Monash University, 19 Rainforest Walk, Clayton, VIC 3800, Australia, Department of Materials Science and Engineering, Monash University, Clayton, VIC 3800, Australia
Maarten Rubens - Polymer Reaction Design Group, School of Chemistry, Monash University, 19 Rainforest Walk, Clayton, VIC 3800, Australia, Hasselt University, Materlarenlaan 42, 3500 Hasselt, Belgium
Neil R. Cameron - Department of Materials Science and Engineering, Monash University, Clayton, VIC 3800, Australia, School of Engineering, University of Warwick, Coventry CV4 7AL, UK
Tanja Junkers - Polymer Reaction Design Group, School of Chemistry, Monash University, 19 Rainforest Walk, Clayton, VIC 3800, Australia, Hasselt University, Materlarenlaan 42, 3500 Hasselt, Belgium
Détails de publication: Polymer chemistry, Vol.13(10), pp.1387-1393
Nombre de pages: 7
Identifiants: 99139216209311
Unité académique: Institut Charles Gerhardt Montpellier - ICGM
Langue: English
Type de ressource: Journal article