Novel Synthetic Approach to Arylboronates via Rhodium-Catalyzed Carbon–Cyano Bond Cleavage of Nitriles

Hirotaka Kinuta; Yusuke Kita; Emmanuelle Rémond; Mamoru Tobisu; Naoto Chatani

doi:10.1055/s-0031-1290370

Retour

Novel Synthetic Approach to Arylboronates via Rhodium-Catalyzed Carbon–Cyano Bond Cleavage of Nitriles

Article de revue

Avec comité de lecture

Novel Synthetic Approach to Arylboronates via Rhodium-Catalyzed Carbon–Cyano Bond Cleavage of Nitriles

Hirotaka Kinuta, Yusuke Kita, Emmanuelle Rémond, Mamoru Tobisu et Naoto Chatani

Synthesis (Stuttgart), Vol.44(19), pp.2999-3002

02/10/2012

DOI: https://doi.org/10.1055/s-0031-1290370

Résumé

practical synthetic procedures

Abstract A new rhodium-catalyzed method for preparing arylboronates from aryl cyanides through the cleavage of carbon–cyano bonds is described. This unprecedented transformation of nitriles allows the use of a cyano group as a boryl equivalent and the regioselective introduction of a boryl group at a late stage of the synthesis.

Indicateurs

1 Consultations de la notice

Détails

Titre: Novel Synthetic Approach to Arylboronates via Rhodium-Catalyzed Carbon–Cyano Bond Cleavage of Nitriles
Créateurs - sans rôle: Hirotaka Kinuta - Department of Applied Chemistry, Faculty of Engineering, Osaka University
Yusuke Kita - Department of Applied Chemistry, Faculty of Engineering, Osaka University
Emmanuelle Rémond - Department of Applied Chemistry, Faculty of Engineering, Osaka University
Mamoru Tobisu - Center for Atomic and Molecular Technologies, Graduate School of Engineering, Osaka University
Naoto Chatani - Department of Applied Chemistry, Faculty of Engineering, Osaka University
Détails de publication: Synthesis (Stuttgart), Vol.44(19), pp.2999-3002
Éditeur: Georg Thieme Verlag
Nombre de pages: 4
Identifiants: 99138992209311
Unité académique: Institut des Biomolécules Max Mousseron - IBMM
Langue: English
Type de ressource: Journal article