Abstract
The copper-catalyzed alkyne azide cycloaddition (CuAAC) reaction was combined with sol-gel reactions for the production of bridged silsesquioxanes (BSs) in which hexyl and icosanyl chains are pendant and anchored on a single position to a triazole ring. The influence of the alkyl chain length on the structure of the BSs, represented by the notation Cn/ siloxane (where n = 6 and 20), was examined. The C20/siloxane hybrid is a hydrophobic material that exhibits a hierarchically structured lamellar bilayer organization, a texturecomposed of microplates of nanometer thickness, and a reversible time-independent order/disorder phase transition (onset at 60 °C). The driving forces for self-assembly are van der Waals interactions between the icosanyl chains and π-π interactions between the triazole rings. In the essentially amorphous C6/siloxane hybrid, the latter contribution promotesthe genesis of a pre-lamellar phase similar to that found in C20/siloxane.