N-p-methoxybenzylidene derivatives of 2-amino-2-deoxy- d-glucose as glycosyl donors: a reinvestigation

Alberto Marra; Pierre Sinaÿ

doi:10.1016/0008-6215(90)84200-E

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N-p-methoxybenzylidene derivatives of 2-amino-2-deoxy- d-glucose as glycosyl donors: a reinvestigation

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N-p-methoxybenzylidene derivatives of 2-amino-2-deoxy- d-glucose as glycosyl donors: a reinvestigation

Alberto Marra et Pierre Sinaÿ

Carbohydrate research, Vol.200(C), pp.319-337

25/04/1990

DOI: https://doi.org/10.1016/0008-6215(90)84200-E

PMID: 2379211

Résumé

6- O-Acetyl-3,4-di- O-benzyl-2-deoxy-2- p-methoxybenzylideneamino- d-glucopyranosyl chloride, 3,4,6-tri- O-acetyl-2-deoxy-2- p-methoxybenzylideneamino-α- d-glucopyranosyl bromide, 3,4,6-tri- O-acetyl-2-deoxy-2- p-methoxybenzylideneamino-α- and -β- d-glucopyranosyl trichloroacetimidate, and 3,4,6-tri- O-acetyl-2-deoxy-2- p-nitrobenzylideneamino-α- d-glucopyranosyl bromide have been synthesised, and their behaviour as glycosylation agents with various soluble promoters has been investigated. The results obtained question the accepted non-participating character of the N-p-methoxybenzylideneamino group.

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Détails

Titre: N-p-methoxybenzylidene derivatives of 2-amino-2-deoxy- d-glucose as glycosyl donors: a reinvestigation
Créateurs - sans rôle: Alberto Marra
Pierre Sinaÿ
Détails de publication: Carbohydrate research, Vol.200(C), pp.319-337
Éditeur: Elsevier Ltd
Nombre de pages: 19
Identifiants: 99163336309311
Unité académique: Institut des Biomolécules Max Mousseron - IBMM
Langue: English
Type de ressource: Journal article