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MgI 2 -Mediated Chemoselective Cleavage of Protecting Groups: An Alternative to Conventional Deprotection Methodologies
Journal article   Peer reviewed

MgI 2 -Mediated Chemoselective Cleavage of Protecting Groups: An Alternative to Conventional Deprotection Methodologies

Mathéo Berthet, Florian Davanier, Gilles Dujardin, Jean Martinez and Isabelle Parrot
Chemistry - A European Journal, Vol.21(31), pp.11014-11016
27/07/2015
PMID: 26121554

Abstract

carbamates cleavage reactions esters protecting groups solid-phase synthesis Amino Acids Esterification Esters Green Chemistry Technology Iodides Magnesium Compounds Solid-Phase Synthesis Techniques Solvents
The scope of MgI2 as a valuable tool for quantitative and mild chemoselective cleavage of protecting groups is described here. This novel synthetic approach expands the use of protecting groups, widens the concept of orthogonality in synthetic processes, and offers a facile opportunity to release compounds from solid supports.
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