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Lewis Acid Catalyzed Three-Component [3+2] Cycloaddition Reaction Using Pentafulvene as 2π Component: An Easy Way to Construct Pentaleno(1,2-b)indoles
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Lewis Acid Catalyzed Three-Component [3+2] Cycloaddition Reaction Using Pentafulvene as 2π Component: An Easy Way to Construct Pentaleno(1,2-b)indoles

P. V. Santhini, S. Sarath Chand, Jubi John, R. Luxmi Varma, Florian Jaroschik et K. V. Radhakrishnan
Synlett, Vol.28(8), pp.951-956
12/05/2017
DOI: https://doi.org/10.1055/s-0036-1588696

Résumé

Chemistry Chemistry, Organic Physical Sciences Science & Technology
A facile route toward the synthesis of pentaleno(1,2-b) in-doles via multicomponent reaction of indole, aldehyde, and pentafulvene is realized. The reaction proceeds through Lewis acid catalyzed [3+2] cycloaddition of in situ generated indolylmethanol and pentafulvene. This methodology provides an easy access to biologically relevant indole derivatives.

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