Abstract
Proton exchange membrane fuel cells (PEMFCs) are an attractive green technology for energy production. However, one of their mayor drawbacks is the instability of the electrolytes under working conditions (i.e., temperature and humidity). Some Metal-Organic Frameworks (MOFs) have recently emerged as promising alternative electrolyte materials due to their higher stability 2 (compared with the organic polymers, currently used as electrolyte), proton conductivity and outstanding porosity and versatility. Here, we present the ionic exchange in a microporous zirconium phosphonate UPG-1 as an efficient strategy to enhance its conductivity and cyclability. Thus, labile protons of the hybrid structure were successfully replaced by different alkali cations (Li + , Na + and K +), leading to two magnitude orders higher proton conductivity than the pristine UPG-1 (up to 2.3•10-2 S•cm-1 , which is comparable with those of the commercial electrolytes). Further, proton conductivity was strongly influenced by the MOF hydrophilicity and the polarization strength of cation, as suggested by molecular simulation. Finally, a mixed matrix membrane containing the best performing material (the potassium exchanged one) was successfully prepared, showing moderate proton conductivity (up to 8.51 10-3 S•cm-1).