Generation and Structural Characterization of a Gold(III) Alkene Complex

Eirin Langseth; Margaret L. Scheuermann; David Balcells; Werner Kaminsky; Karen I. Goldberg; Odile Eisenstein; Richard N. Heyn; Mats Tilset

doi:10.1002/anie.201209140

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Generation and Structural Characterization of a Gold(III) Alkene Complex

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Generation and Structural Characterization of a Gold(III) Alkene Complex

Eirin Langseth, Margaret L. Scheuermann, David Balcells, Werner Kaminsky, Karen I. Goldberg, Odile Eisenstein, Richard N. Heyn and Mats Tilset

Angewandte Chemie International Edition, Vol.52, pp.1660-1663

02/01/2013

DOI: https://doi.org/10.1002/anie.201209140

Abstract

A Missing Gold Link: An Au(III) alkene complex has been prepared and characterized by NMR spectroscopy and X-ray crystallography. Its bonding features have been analyzed by DFT calculations and natural bond orbital (NBO) analysis. In [(cod)AuMe(2) ](+) , the unequal AuC bond lengths result from the domination of the preference of 1,5-cyclooctadiene (cod) for nonparallel double bonds over back donation from the metal which favors parallel double bonds.

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Title: Generation and Structural Characterization of a Gold(III) Alkene Complex
Creators - without role: Eirin Langseth - University of Oslo
Margaret L. Scheuermann - University of Washington
David Balcells - University of Oslo
Werner Kaminsky - University of Washington
Karen I. Goldberg - University of Washington
Odile Eisenstein - Université de Montpellier, Institut Charles Gerhardt Montpellier - ICGM
Richard N. Heyn
Mats Tilset - University of Oslo
Publication Details: Angewandte Chemie International Edition, Vol.52, pp.1660-1663
Identifiers: 9944867609311
Academic Unit: Institut Charles Gerhardt Montpellier - ICGM
Language: English
Resource Type: Journal article
Local Fields: hal-00785548