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First radical homopolymerisation of 2-trifluoromethacrylic acid in water and study of the degradation of the resulting homopolymers
Article de revue   Avec comité de lecture

First radical homopolymerisation of 2-trifluoromethacrylic acid in water and study of the degradation of the resulting homopolymers

Yogesh Patil, Hisao Hori, Hirotaka Tanaka, Takehiko Sakamoto et Bruno Ameduri
Chemical communications (Cambridge, England), Vol.49(59), pp.6662-6664
01/01/2013
DOI: https://doi.org/10.1039/c3cc42395f
PMID: 23770575

Résumé

Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology
The radical homopolymerisation of 2-trifluoromethacrylic acid (MAF) initiated by Na2S2O8 in water, under the influence of pH, led to original water soluble surfactants, the decomposition of which was investigated. The value of the square of the propagation rate constant to the termination rate constant, k(p)(2)/k(te), of MAF was 4 x 10(-3) l mol(-1) s(-1) at 80 degrees C.

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