First observation of [Pu6(OH)4O4 ]12+ cluster during the hydrolytic formation of PuO2 nanoparticles using H/D kinetic isotope effect

Manon Cot-Auriol; Matthieu Virot; Thomas Dumas; Olivier Diat; Denis Menut; Philippe Moisy; Sergey Nikitenko

doi:10.1039/D2CC04990B

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First observation of [Pu6(OH)4O4 ]12+ cluster during the hydrolytic formation of PuO2 nanoparticles using H/D kinetic isotope effect

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First observation of [Pu6(OH)4O4 ]12+ cluster during the hydrolytic formation of PuO2 nanoparticles using H/D kinetic isotope effect

Manon Cot-Auriol, Matthieu Virot, Thomas Dumas, Olivier Diat, Denis Menut, Philippe Moisy and Sergey Nikitenko

Chemical Communications, Vol.58(94), pp.13147-13150

24/11/2022

DOI: https://doi.org/10.1039/D2CC04990B

Abstract

New insights are provided about the formation mechanism of PuO2 nanoparticles (NPs) by investigating an unprecedented kinetic isotope effect observed during their hydrolytic synthesis in H2O or D2O media.

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Title: First observation of [Pu6(OH)4O4 ]12+ cluster during the hydrolytic formation of PuO2 nanoparticles using H/D kinetic isotope effect
Creators - without role: Manon Cot-Auriol - CEA Marcoule
Matthieu Virot - CEA Marcoule
Thomas Dumas - CEA Marcoule
Olivier Diat - CEA Marcoule
Denis Menut - Synchrotron soleil
Philippe Moisy - Commissariat à l'Énergie Atomique et aux Énergies Alternatives
Sergey Nikitenko - CEA Marcoule
Publication Details: Chemical Communications, Vol.58(94), pp.13147-13150
Identifiers: 9939475809311
Academic Unit: Institut de Chimie Séparative de Marcoule - ICSM
Language: English
Resource Type: Journal article
Local Fields: hal-03916056