Enhanced H2 Uptake in Solvents Confined in Mesoporous Metal− Organic Framework

Stephanie Clauzier; Linh Ngoc Ho; Marc Pera-Titus; Benoit Coasne; D. Farrusseng

doi:10.1021/ja308157a

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Enhanced H2 Uptake in Solvents Confined in Mesoporous Metal− Organic Framework

Journal article

Peer reviewed

Enhanced H2 Uptake in Solvents Confined in Mesoporous Metal− Organic Framework

Stephanie Clauzier, Linh Ngoc Ho, Marc Pera-Titus, Benoit Coasne and D. Farrusseng

Journal of the American Chemical Society, Vol.134

08/10/2012

DOI: https://doi.org/10.1021/ja308157a

Abstract

Hydrogen uptake at 298 K and 30 bar in hybrid sorbents consisting of n-hexane confined in MIL-101 is found to be 22 times larger than in sole n-hexane. The enhanced solubility in MIL-101, found to be 3 times larger than in mesoporous silica of similar pore size, highlights the key roles played by surface chemistry and accessible surface area.

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Title: Enhanced H2 Uptake in Solvents Confined in Mesoporous Metal− Organic Framework
Creators - without role: Stephanie Clauzier - Université de Lyon
Linh Ngoc Ho - Institut de Recherches sur la Catalyse et l'Environnement de Lyon
Marc Pera-Titus - Centre National de la Recherche Scientifique
Benoit Coasne - Université de Montpellier, Institut Charles Gerhardt Montpellier - ICGM
D. Farrusseng - Université de Lyon
Publication Details: Journal of the American Chemical Society, Vol.134
Grant note: grant from the Région Rhône-Alpes (Cluster 7/ARC) for a doctoral fellowship.
Identifiers: 9944980109311
Academic Unit: Institut Charles Gerhardt Montpellier - ICGM
Language: English
Resource Type: Journal article
Local Fields: hal-00790058