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Efficient and eco-compatible transition metal-free Oppenauer-type oxidation of alcohols
Journal article   Peer reviewed

Efficient and eco-compatible transition metal-free Oppenauer-type oxidation of alcohols

Jorge Ballester, Anne-Marie Caminade, Jean Pierre Majoral, Marc Taillefer and Armelle Ouali
Catalysis Communications, Vol.47, pp.58-62
04/01/2014

Abstract

Ketone Sodium tert-butoxide Catalysis Oxidation Alcohol Oppenauer
Catalytic amounts of cheap, non-toxic, easy-to-handle and non-sensitive sodium tert-butoxide are able to promote the dehydrogenative oxidation of a wide array of secondary alcohols using inexpensive benzophenone as the H-acceptor. The corresponding ketones, highly important intermediates and targets throughout life and material sciences, are very selectively obtained under mild conditions
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