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Efficient Synthesis of Tris(acetonitrile)-(h5-cyclopentadienyl)- ruthenium(II) Hexafluorophosphate via Ruthenocene
Article de revue   Avec comité de lecture

Efficient Synthesis of Tris(acetonitrile)-(h5-cyclopentadienyl)- ruthenium(II) Hexafluorophosphate via Ruthenocene

Florian Monnier et E. Peter Kundig
Advanced synthesis & catalysis, Vol.346(346), pp.901-904
07/2004
DOI: https://doi.org/10.1002/adsc.200404124

Résumé

Catalysis Chemical Sciences Organic chemistry
[Ru(h5-C5H5)(CH3CN)3][PF6] (1), a versatile precursor to catalysts containing the CpRuþ complex fragment, can be obtained in high yield via Cp/naphthalene exchange in ruthenocene. This new route via the complex [RuCp(naphthalene)]- [PF6] (4) avoids both highly toxic thallium reagents and the need for a photoreactor.

Indicateurs

1 Consultations de la notice

Détails

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