Double [3 + 2]-dimerisation cascade synthesis of bis(triazolyl)bisphosphanes, a new scaffold for bidentate bisphosphanes

Coralie Laborde; Muh-Mei Wei; Arie van Der Lee; Éric Deydier; Jean-Claude Daran; Jean-Noël Null Volle; Rinaldo Poli; Jean-Luc Pirat; Eric Manoury; David Virieux

doi:10.1039/C5DT02197A

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Double [3 + 2]-dimerisation cascade synthesis of bis(triazolyl)bisphosphanes, a new scaffold for bidentate bisphosphanes

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Double [3 + 2]-dimerisation cascade synthesis of bis(triazolyl)bisphosphanes, a new scaffold for bidentate bisphosphanes

Coralie Laborde, Muh-Mei Wei, Arie van Der Lee, Éric Deydier, Jean-Claude Daran, Jean-Noël Null Volle, Rinaldo Poli, Jean-Luc Pirat, Eric Manoury and David Virieux

Dalton Transactions, Vol.44, pp.12539-12545

16/06/2015

DOI: https://doi.org/10.1039/C5DT02197A

Abstract

A highly convergent synthesis of bis(triazolylphosphane oxides) was developed by a tandem copper-mediated Huisgen reaction–oxidative coupling. The phosphane oxides were reduced by trichlorosilane and the coordination of the resulting bisphosphanes was studied with various transition metals.

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Title: Double [3 + 2]-dimerisation cascade synthesis of bis(triazolyl)bisphosphanes, a new scaffold for bidentate bisphosphanes
Creators - without role: Coralie Laborde - Université de Montpellier, Institut Charles Gerhardt Montpellier - ICGM
Muh-Mei Wei - Laboratoire de Chimie de Coordination
Arie van Der Lee - Université de Montpellier, Institut Européen des Membranes - IEM
Éric Deydier - Université de Toulouse
Jean-Claude Daran - Laboratoire de Chimie de Coordination
Jean-Noël Null Volle - Université de Montpellier, Institut Charles Gerhardt Montpellier - ICGM
Rinaldo Poli - Laboratoire de Chimie de Coordination
Jean-Luc Pirat - Université de Montpellier, Institut Charles Gerhardt Montpellier - ICGM
Eric Manoury - Laboratoire de Chimie de Coordination
David Virieux - Université de Montpellier, Institut Charles Gerhardt Montpellier - ICGM
Publication Details: Dalton Transactions, Vol.44, pp.12539-12545
Identifiers: 9934444809311
Academic Unit: Institut Charles Gerhardt Montpellier - ICGM; Institut Européen des Membranes - IEM
Language: English
Resource Type: Journal article
Local Fields: hal-01203779