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Discontinuous change in smectic layer thickness in ferrielectric liquid crystals
Journal article   Peer reviewed

Discontinuous change in smectic layer thickness in ferrielectric liquid crystals

V.P. Panov, J.K. Vij, Yu.P. Panarin, Christophe Blanc, Vladimir Lorman and J.W. Goodby
Physical Review E : Statistical, Nonlinear, and Soft Matter Physics, Vol.75(4)
09/04/2007

Abstract

antiferroelectricity liquid films smectic liquid crystals liquid crystal phase transformations ferroelectric transitions ferroelectric thin films PACS: 64.70.Md; 61.30.Cz; 61.30.Eb; 77.80.-e
The temperature dependence of the thickness of thick free-standing films is studied using a high-resolution film thickness measurement technique. A small discontinuity in the temperature dependence of the smectic layer thickness at every phase transition between ferro-, ferri-, and antiferroelectric phases is observed. We show that the major contribution to it arises from a change in the smectic tilt angle.
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