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Direct Copper-Catalyzed α-Arylation of Benzyl Phenyl Ketones with Aryl Iodides: Route towards Tamoxifen
Journal article   Open access   Peer reviewed

Direct Copper-Catalyzed α-Arylation of Benzyl Phenyl Ketones with Aryl Iodides: Route towards Tamoxifen

Grégory Danoun, Anis Tlili, Florian Monnier and Marc Taillefer
Angewandte Chemie International Edition, Vol.51(51)
09/11/2012

Abstract

arenes copper homogeneous catalysis ketones synthetic methods
The first efficient method for direct α-arylation of non-activated or non-protected family of enolizable ketones with simple aryl iodides employs a catalytic copper system. The method shows potential for the easy and step-economical synthesis of tamoxifen, the most commonly administrated drug for the management of breast cancer.
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