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Diastereoselective addition of 2H-2-oxo-1,4,2-oxazaphosphinanes to aldehydes and imines
Journal article   Peer reviewed

Diastereoselective addition of 2H-2-oxo-1,4,2-oxazaphosphinanes to aldehydes and imines

Jean-Luc Pirat, Jérôme Mombrun, David Null Virieux, Jean-Noël Null Volle, Monique Tillard and Henri-Jean Cristau
Journal of Organic Chemistry, Vol.70(18), pp.7035-7041
2005

Abstract

Diastereoselective additions of 2-hydrogeno-2-oxo-1,4,2-oxazaphosphinanes to aldehydes and imines are described. R,R¢-Diaminophosphinic and R-amino-R¢-hydroxyphosphinic derivatives were obtained with de's ranging from 24 to 90%.
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