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Cover Picture: Conversion of Ammonia to Hydrazine Induced by High‐Frequency Ultrasound (Angew. Chem. Int. Ed. 48/2021)
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Cover Picture: Conversion of Ammonia to Hydrazine Induced by High‐Frequency Ultrasound (Angew. Chem. Int. Ed. 48/2021)

Anaelle Humblot, Laurie Grimaud, Audrey Allavena, Prince N. Amaniampong, Karine De Oliveira Vigier, Tony Chave, Stéphane Streiff et François Jérôme
Angewandte Chemie International Edition, Vol.60(48), pp.25165-25165
22/11/2021

Résumé

ammonia cavitation bubbles hydrazine radicals ultrasound
Ammonia has been converted into hydrazine, a chemical of utmost importance for organic synthesis and energy purposes. In their Communication on page 25230, François Jérôme et al. report that cavitation bubbles, created by ultrasonic irradiation of aqueous ammonia at a high frequency, act as microreactors to activate and convert ammonia into hydrazine at the gas–liquid interface. Maintaining the aqueous solution close to 30 °C prevents the degradation of in situ produced hydrazine.

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