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Cover Feature: Metal‐Dependent and Selective Crystallization of CAU‐10 and MIL‐53 Frameworks through Linker Nitration (Chem. Eur. J. 28/2021)
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Cover Feature: Metal‐Dependent and Selective Crystallization of CAU‐10 and MIL‐53 Frameworks through Linker Nitration (Chem. Eur. J. 28/2021)

Timo Rabe, Erik Svensson Grape, Tobias A. Engesser, A. Ken Inge, Jonas Ströh, Gitta Kohlmeyer-Yilmaz, Mohammad Wahiduzzaman, Guillaume Maurin, Frank D. Sönnichsen et Norbert Stock
Chemistry : a European journal, Vol.27(28), pp.7591-7591
17/05/2021

Résumé

aluminium framework flexibility gallium molecular simulations water adsorption
Starting from 5‐hydroxyisophthalic acid (not shown), in situ nitration leads to different nitrated linker molecules that selectively react with Ga3+ or Al3+ ions to Ga‐MIL‐53 and Al‐CAU‐10 type frameworks, respectively. The pale blue and orange light path represents the crystallization of the respective MOF. More information can be found in the Full Paper by N. Stock et al. (DOI: 10.1002/chem.202100373).

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