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Chiral Aryl-Copper(III) Electrophiles: New Opportunities in Catalytic Enantioselective Arylations and Domino Processes
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Chiral Aryl-Copper(III) Electrophiles: New Opportunities in Catalytic Enantioselective Arylations and Domino Processes

Sophie Rousseaux, Emmanuel Vrancken and Jean-Marc Campagne
Angewandte Chemie International Edition
23/09/2012

Abstract

"Chiral aryl cation" equivalents: The combination of diaryliodonium salts and catalytic amounts of chiral copper com- plexes provides facile access to "chiral 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim These are not the final page numbers! aryl cation" synthons. These reagents offer new possibilities for asymmetric arylation reactions that initiate further domino processes.
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