Calcium-catalysed synthesis of amines through imine hydrosilylation: an experimental and theoretical study

Yougourthen Boumekla; Fengjie Xia; Lucas Vidal; Cédric Totée; Christophe Raynaud; Armelle Ouali

doi:10.1039/d2ob02243e

Back

Calcium-catalysed synthesis of amines through imine hydrosilylation: an experimental and theoretical study

Journal article

Open access

Peer reviewed

Calcium-catalysed synthesis of amines through imine hydrosilylation: an experimental and theoretical study

Yougourthen Boumekla, Fengjie Xia, Lucas Vidal, Cédric Totée, Christophe Raynaud and Armelle Ouali

Organic & Biomolecular Chemistry, Vol.21, pp.1038-1045

01/02/2023

DOI: https://doi.org/10.1039/d2ob02243e

Abstract

Ca(NTf 2 )PF 6 , generated from commercial precursors, promotes imine hydrosilylation in high yields and is used to prepare a bioactive amine on the gram scale. The mechanistic investigations highlight an unprecedented Si–H activation by the Ca center.

Files and links (2)

url

Find in HALView

url

https://doi.org/10.1039/d2ob02243eView

Published (Version of record) Open

Metrics

1 Record Views

Details

Title: Calcium-catalysed synthesis of amines through imine hydrosilylation: an experimental and theoretical study
Creators - without role: Yougourthen Boumekla - Université de Montpellier, Institut Charles Gerhardt Montpellier - ICGM
Fengjie Xia - Université de Montpellier, Institut Charles Gerhardt Montpellier - ICGM
Lucas Vidal - Université de Montpellier, Institut Charles Gerhardt Montpellier - ICGM
Cédric Totée - Université de Montpellier, Institut Charles Gerhardt Montpellier - ICGM
Christophe Raynaud - Université de Montpellier, Institut Charles Gerhardt Montpellier - ICGM
Armelle Ouali - Université de Montpellier, Institut Charles Gerhardt Montpellier - ICGM
Publication Details: Organic & Biomolecular Chemistry, Vol.21, pp.1038-1045
Identifiers: 9945940709311
Academic Unit: Institut Charles Gerhardt Montpellier - ICGM
Language: English
Resource Type: Journal article
Local Fields: hal-03967685