Cage-like Fe,Na-Germsesquioxanes: Structure, Magnetism, and Catalytic Activity

Alexey Bilyachenko; Mikhail Levitsky; Alexey Yalymov; Alexander Korlyukov; Viktor Khrustalev; Anna Vologzhanina; Lidia Shul'Pina; Nikolay Ikonnikov; Alexander Trigub; Pavel Dorovatovskii; Xavier Bantreil; Frédéric Lamaty; Jérôme Long; Joulia Larionova; Igor Golub; Elena Shubina; Georgiy Shul'Pin

doi:10.1002/ange.201607189

Back

Cage-like Fe,Na-Germsesquioxanes: Structure, Magnetism, and Catalytic Activity

Journal article

Open access

Peer reviewed

Cage-like Fe,Na-Germsesquioxanes: Structure, Magnetism, and Catalytic Activity

Alexey Bilyachenko, Mikhail Levitsky, Alexey Yalymov, Alexander Korlyukov, Viktor Khrustalev, Anna Vologzhanina, Lidia Shul'Pina, Nikolay Ikonnikov, Alexander Trigub, Pavel Dorovatovskii, …

Angewandte Chemie, Vol.128(49), pp.15586-15589

2016

DOI: https://doi.org/10.1002/ange.201607189

Abstract

A series of four unprecedented heterometallic metallagermsesquioxanes were synthesized. Their cage‐like architectures have a unique type of molecular topology consisting of the hexairon oxo {Fe6O19} core surrounded in a triangular manner by three cyclic germoxanolates [PhGe(O)O]5. This structural organization induces antiferromagnetic interactions between the FeIII ions through the oxygen atoms. Evaluated for this first time in catalysis, these compounds showed a high catalytic activity in the oxidation of alkanes and the oxidative formation of benzamides from alcohols.

Files and links (1)

url

Find in HALView

Metrics

1 Record Views

Details

Title: Cage-like Fe,Na-Germsesquioxanes: Structure, Magnetism, and Catalytic Activity
Creators - without role: Alexey Bilyachenko - A. N. Nesmeyanov Institute of Organoelement Compounds
Mikhail Levitsky - A. N. Nesmeyanov Institute of Organoelement Compounds
Alexey Yalymov - A. N. Nesmeyanov Institute of Organoelement Compounds
Alexander Korlyukov - A. N. Nesmeyanov Institute of Organoelement Compounds
Viktor Khrustalev - A. N. Nesmeyanov Institute of Organoelement Compounds
Anna Vologzhanina - A. N. Nesmeyanov Institute of Organoelement Compounds
Lidia Shul'Pina - A. N. Nesmeyanov Institute of Organoelement Compounds
Nikolay Ikonnikov - A. N. Nesmeyanov Institute of Organoelement Compounds
Alexander Trigub - Kurchatov Institute
Pavel Dorovatovskii
Xavier Bantreil - Université de Montpellier, Institut des Biomolécules Max Mousseron - IBMM
Frédéric Lamaty - Université de Montpellier, Institut des Biomolécules Max Mousseron - IBMM
Jérôme Long - Université de Montpellier, Institut Charles Gerhardt Montpellier - ICGM
Joulia Larionova - A. N. Nesmeyanov Institute of Organoelement Compounds
Igor Golub - A. N. Nesmeyanov Institute of Organoelement Compounds
Elena Shubina - A. N. Nesmeyanov Institute of Organoelement Compounds
Georgiy Shul'Pin - A. N. Nesmeyanov Institute of Organoelement Compounds
Publication Details: Angewandte Chemie, Vol.128(49), pp.15586-15589
Identifiers: 9947277609311
Academic Unit: Institut Charles Gerhardt Montpellier - ICGM; Institut des Biomolécules Max Mousseron - IBMM
Language: English
Resource Type: Journal article
Local Fields: hal-03079229