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Bidirectional Nanoparticle Crossing of Oil-Water Interfaces Induced by Different Stimuli: Insight into Phase Transfer
Journal article   Open access   Peer reviewed

Bidirectional Nanoparticle Crossing of Oil-Water Interfaces Induced by Different Stimuli: Insight into Phase Transfer

Antonio Stocco, Munish Chanana, Ge Su, Peter Cernoch, Bernard P Binks and Dayang Wang
Angewandte Chemie International Edition, Vol.51(38)
17/09/2012

Abstract

interfaces nanoparticles phase transfer soft matter
Swap transactions: Bidirectional spontaneous transfer of gold nanoparticles coated with stimuli-responsive polymer brushes across oil-water interfaces has been implemented. The water-to-oil transfer of the gold nanoparticles is dictated by the ionic strength in water, while the nanoparticle oil-to-water transfer occurs only when the environmental temperature is reduced below 5 °C.
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