Anthradithiophene Derivatives Substituted at the 2,8-Positions by Formyl and Triphenylamine Units: Synthesis, Optical, and Electrochemical Properties

Jean-Yves Balandier; Noham Sebaihi; Pol Boudard; Vincent Lemaur; Florence Quist; Claude Niebel; Sara Stas; Benoit Tylleman; Roberto Lazzaroni; Jerome Cornil; Yves Henri Geerts

doi:10.1002/ejoc.201100401

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Anthradithiophene Derivatives Substituted at the 2,8-Positions by Formyl and Triphenylamine Units: Synthesis, Optical, and Electrochemical Properties

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Anthradithiophene Derivatives Substituted at the 2,8-Positions by Formyl and Triphenylamine Units: Synthesis, Optical, and Electrochemical Properties

Jean-Yves Balandier, Noham Sebaihi, Pol Boudard, Vincent Lemaur, Florence Quist, Claude Niebel, Sara Stas, Benoit Tylleman, Roberto Lazzaroni, Jerome Cornil, …

European journal of organic chemistry, Vol.2011(17), pp.3131-3136

06/2011

DOI: https://doi.org/10.1002/ejoc.201100401

Résumé

Chemistry

Chemistry, Organic

Physical Sciences

Science & Technology

The synthesis and characterization of two new anthradithiophene (ADT) derivatives substituted by thiophenyl or 2-octylthiophenyl units at the 5,11-positions and donor (triphenylamine) or acceptor (aldehyde functions) moieties at the 2,8-positions of their backbone are described. Optical measurements were performed to evaluate the effect of electron-rich/-poor substituents on their stability towards photo-oxidation and were supported by quantum chemical calculations and cyclic voltammetry experiments.

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Titre: Anthradithiophene Derivatives Substituted at the 2,8-Positions by Formyl and Triphenylamine Units: Synthesis, Optical, and Electrochemical Properties
Créateurs - sans rôle: Jean-Yves Balandier - Univ Libre Bruxelles, Lab Chim Polymeres, Fac Sci, B-1050 Brussels, Belgium
Noham Sebaihi - University of Mons
Pol Boudard - University of Mons
Vincent Lemaur - Univ Mons UMONS, Serv Chim Mat Nouveaux, B-7000 Mons, Belgium
Florence Quist - Univ Libre Bruxelles, Lab Chim Polymeres, Fac Sci, B-1050 Brussels, Belgium
Claude Niebel - Univ Libre Bruxelles, Lab Chim Polymeres, Fac Sci, B-1050 Brussels, Belgium
Sara Stas - Univ Libre Bruxelles, Lab Chim Polymeres, Fac Sci, B-1050 Brussels, Belgium
Benoit Tylleman - Univ Libre Bruxelles, Lab Chim Polymeres, Fac Sci, B-1050 Brussels, Belgium
Roberto Lazzaroni - University of Mons
Jerome Cornil - University of Mons
Yves Henri Geerts - Univ Libre Bruxelles, Lab Chim Polymeres, Fac Sci, B-1050 Brussels, Belgium
Détails de publication: European journal of organic chemistry, Vol.2011(17), pp.3131-3136
Éditeur: Wiley
Nombre de pages: 6
Note de subvention: OPTI2MAT Excellence Program Belgian National Fund for Scientific Research - Fonds de la Recherche Collective (FRFC); Fonds de la Recherche Scientifique - FNRS
Identifiants: 99158382709311
Unité académique: Institut Charles Gerhardt Montpellier - ICGM
Langue: English
Type de ressource: Journal article