Abstract
The adsorption of carbon dioxide and methane in nanoporous carbons in the presence of water is studied using experiments and molecular simulations. For all amounts of adsorbed water molecules, the adsorption isotherms for carbon dioxide and methane resemble those obtained for pure fluids. The pore filling mechanism does not seem to be affected by the presence of the water molecules. Moreover, the pressure at which the maximum adsorbed amount of methane or carbon dioxide is reached is nearly insensitive to the loading of preadsorbed water molecules. In contrast, the adsorbed amount of methane or carbon dioxide decreases linearly with the number of guest water molecules. Typical molecular configurations obtained using molecular simulation indicate that the water molecules form isolated clusters within the host porous carbon due to the nonfavorable interaction between carbon dioxide or methane and water.